A Complete Guide to Acid and Base Nomenclature

Expert reviewed 22 November 2024 6 minute read


Understanding how to name acids and bases is fundamental to chemistry. This guide covers the systematic naming conventions for inorganic acids and bases, following IUPAC standards.

Classification of Acids

Inorganic acids fall into two main categories:

  • Binary Acids: These acids don't contain oxygen and include hydrohalic acids
  • Oxoacids: These contain oxygen along with hydrogen and another element

Binary Acids (Hydrohalic Acids)

Binary acids form when hydrogen combines with halogens (Group 17 elements). Their naming follows this pattern:

hydro- + halogen name + -ic acid

Examples:

  • HF → Hydrofluoric acid
  • HCl → Hydrochloric acid
  • HBr → Hydrobromic acid
  • HI → Hydroiodic acid

Oxoacids

Oxoacids contain three elements:

  • Hydrogen (H)
  • Oxygen (O)
  • A central element (E)

Non-halogenic Oxoacids

The naming convention uses two suffixes:

  • "-ic": More oxygen atoms
  • "-ous": Fewer oxygen atoms

Common examples:

Central ElementMore OxygenLess Oxygen
NitrogenNitric acid (HNO3\mathrm{HNO_3})Nitrous acid (HNO2\mathrm{HNO_2})
PhosphorusPhosphoric acid (H3PO4\mathrm{H_3PO_4})Phosphorous acid (H3PO3\mathrm{H_3PO_3})
SulfurSulfuric acid (H2SO4\mathrm{H_2SO_4})Sulfurous acid (H2SO3\mathrm{H_2SO_3})

Halogenic Oxoacids

These follow a four-level naming system based on oxygen content:

  • per- + element + -ic acid (most oxygen)
  • element + -ic acid
  • element + -ous acid
  • hypo- + element + -ous acid (least oxygen)

Example with chlorine:

  • HClO4\mathrm{HClO_4} → Perchloric acid
  • HClO3\mathrm{HClO_3} → Chloric acid
  • HClO2\mathrm{HClO_2} → Chlorous acid
  • HClO\mathrm{HClO} → Hypochlorous acid

Nomenclature of Bases

Inorganic bases follow ionic compound naming rules:

  • Metal Hydroxides:

    • NaOH\mathrm{NaOH} → Sodium hydroxide
    • KOH\mathrm{KOH} → Potassium hydroxide
  • Non-metal Hydroxides:

    • NH4OH\mathrm{NH_4OH} → Ammonium hydroxide
  • Metal Carbonates:

    • NaHCO3\mathrm{NaHCO_3} → Sodium hydrogen carbonate
    • Na2CO3\mathrm{Na_2CO_3} → Sodium carbonate

Common Acids and Bases

Strong vs. Weak Acids

Strong acids completely dissociate in water, while weak acids partially dissociate.

Strong Acids Examples:

  • Perchloric acid (HClO4\mathrm{HClO_4})
  • Hydrochloric acid (HCl\mathrm{HCl})
  • Sulfuric acid (H2SO4\mathrm{H_2SO_4})
  • Nitric acid (HNO3\mathrm{HNO_3})

Weak Acids Examples:

  • Phosphoric acid (H3PO4\mathrm{H_3PO_4})
  • Hydrofluoric acid (HF\mathrm{HF})
  • Acetic acid (CH3COOH\mathrm{CH_3COOH})
  • Citric acid (C6H8O7\mathrm{C_6H_8O_7})

Strong vs. Weak Bases

Strong bases dissociate completely, while weak bases partially dissociate.

Strong Bases Examples:

  • Sodium hydroxide (NaOH\mathrm{NaOH})
  • Potassium hydroxide (KOH\mathrm{KOH})
  • Calcium hydroxide (Ca(OH)2\mathrm{Ca(OH)_2})

Weak Bases Examples:

  • Ammonia (NH3\mathrm{NH_3})
  • Sodium bicarbonate (NaHCO3\mathrm{NaHCO_3})
  • Methylamine (CH3NH2\mathrm{CH_3NH_2})

Return to Module 6: Acid-Base Reactions