Fundamentals of Hydrocarbons: Structure, Properties, and Reactions
Expert reviewed •23 November 2024• 5 minute read
Introduction
Hydrocarbons form the foundation of organic chemistry, consisting exclusively of carbon and hydrogen atoms. These molecules are essential to understanding both natural processes and industrial applications, from the fuel in our vehicles to the plastics we use daily.
Organic Chemistry Fundamentals
Organic chemistry studies carbon-containing compounds, with a few notable exceptions:
Carbon oxides (CO₂, CO)
Carbon-containing ions (like CN⁻)
Carbon's unique ability to form up to four stable covalent bonds makes it the backbone of organic chemistry. This property enables the formation of complex molecules essential for life, including:
Proteins
DNA
Carbohydrates
Lipids
Classification of Hydrocarbons
Hydrocarbons are classified into three main groups:
1. Alkanes
Alkanes are saturated hydrocarbons with the general formula CnH2n+2. Key characteristics include:
Single carbon-carbon bonds (C-C)
Tetrahedral molecular geometry
Bond angles of 109.5°
Maximum hydrogen saturation
Properties:
Low chemical reactivity
Non-polar nature
Intermolecular forces dominated by dispersion
Boiling and melting points increase with molecular mass
Lower solubility in water as chain length increases
The combustion of alkanes follows the general equation:
CnH2n+2+23n+1O2→nCO2+(n+1)H2O
2. Alkenes
Alkenes contain at least one carbon-carbon double bond (C=C) and follow the formula CnH2n. Their structure features:
Trigonal planar geometry around the double bond
Bond angles of 120°
Unsaturated nature
Properties:
Higher reactivity than alkanes
Ability to undergo addition reactions
Slightly lower boiling points than corresponding alkanes
Non-polar nature
3. Alkynes
Alkynes contain at least one carbon-carbon triple bond (C≡C) and follow the formula CnH2n−2. Their structure features:
Linear geometry around the triple bond
Bond angles of 180°
Highly unsaturated nature
Properties:
Highest reactivity among hydrocarbons
Higher melting and boiling points than corresponding alkanes and alkenes
Enhanced intermolecular forces due to easily polarizable electrons
Ability to undergo multiple addition reactions
Structural Effects on Properties
Chain Length:
Longer chains increase boiling and melting points
Decreased water solubility
Enhanced dispersion forces
Branching:
Branched molecules have lower boiling points than straight-chain isomers
Reduced surface area for intermolecular interactions